Why Gold is Precious

The precious metals are those few that are not gasses, and not reactive. Of these, only gold (Au) and silver (Ag) are not extremely rare and hard to extract and work.

A while back, I posted a radio article by Planet Money on why gold is so valuable, and has been used for money for so long (God, Glory and GOLD: but why gold?). They’ve now created a nice video explaining the same thing. Though there’s less detail, the dramatic visuals (of the reactivity of sodium for example) make it quite interesting.

3d Molecule of the Month

Cyclohexane, from the interactive model on 3Dchem.com.

Molecular models tend to fascinate. As a introduction to the chemistry of elements, students seem to like putting them together, and they tend to enjoy finding out what their molecules are called.

You can’t beat fitting together molecules by hand as a learning experience, but 3Dchem has a nice collection of interactive, three-dimensional molecules, including molecules of the month.

Periodic spiral of the elements (from 3Dchem.com).

They also have three-dimensional periodic tables showing the sizes of the atoms in the traditional tabular form as well as a spiral.

Periodic Table showing the elements by size.

Periodic Table Spiral Galaxy

The objective is to show the shape of the whole and to express the beauty and cosmic reach of the periodic system.

— Stewart (2006): The Chemical Galaxy

Chemical Galaxy II: A new vision of the periodic system of the elements by Philip Stewart.
Periodic Table of the Elements - a traditional view by Wikimedia Commons User:Cepheus.

The traditional periodic table of the elements breaks the elements into rows as their chemical and physical characteristics repeat themselves. But since the sequence of elements is really a continuous series that gradually increases in mass, a better way of displaying them might be as the spiral, sort of like the galaxy.

When the chemical elements are arranged in order of their atomic number, they form a continuous sequence, in which certain chemical characteristics come back periodically in a regular way. This is usually shown by chopping the sequence up into sections and arranging them as a rectangular table. The alternative is to wind the sequence round in a spiral. Because the periodic repeats come at longer and longer intervals, increasing numbers of elements have to be fitted on to its coils. …

The resulting pattern resembles a galaxy, and the likeness is the basis of my design. It seems appropriate, as the chemical elements are what galaxies are made of.

The ‘spokes’ of the ‘galaxy’ link together elements with similar chemical characteristics. They are curved in order to keep the inner elements reasonably close together while making room for the extra elements in the outer turns.

— Stewart (2006): The Chemical Galaxy

While the spiral version of the periodic table is not used a lot, it is scientifically valid. There are other ways of representing the spiral and the periodic table itself. It all depends on what you want to show.

Benfey's spiral table first appeared in an article by Glenn Seaborg, 'Plutonium: The Ornery Element', Chemistry, June 1964, 37 (6), 12-17, on p. 14. (via Wikimedia Commons)

Indeed, Mendeleev’s monument in Bratislava, Slovakia has the elements arranged as the spokes in a wheel.

Monument to the periodic table and Dmitri Mendellev (photo by mmmdirt, caption via Wikipedia).

The Uses of Rare Earth Elements

Tiny quantities of dysprosium can make magnets in electric motors lighter by 90 percent, while terbium can help cut the electricity usage of lights by 80 percent.

–Lifton (2010): The Battle Over Rare Earth Metals

There has recently been a bit of a furor over the fact that, currently, China produces 90% of the world’s rare earth metals. Special properties of these elements are making them extremely important in a lot of high-tech and alternative energy technologies.

Fiber-optic cables can transmit signals over long distances because they incorporate periodically spaced lengths of erbium-doped fiber that function as laser amplifiers. Er is used in these laser repeaters, despite its high cost (~$700/kg), because it alone possesses the required optical properties.

–Haxel et al., 2005: Rare Earth Elements—Critical Resources for High Technology

The rare earths are so chemically similar that they’re lumped together in one corner of the periodic table, which is why they have not been used a lot until now. Only recently has their influence on elecromagnetic systems been discovered. Wikipedia has a good list of the elements with some of their uses.

The rare earth elements.

Many people are worried about one country controlling so much of a single resource, especially since China cut its export quotas earlier this year. Fortunately, rare earth metals are found in places other than China, and, as the demand continues to outstrip supply, it’s just a matter of time for high prices to to bring more mining and recycling projects into production.

God, Glory and GOLD: but why gold?

Gold coin of Kumaragupta I. (Image from Wikimedia Commons).

NPR’s Planet Money has a nice story on why gold is used for money. They take the entire periodic table of elements and eliminate the ones that don’t work because they’re too reactive, a gas, too common, or too toxic. You’re left with five precious metals, rhodium, palladium, silver, platinum and gold, but only one of them has a low enough melting temperature so that it can be worked easily and is not ridiculously rare.

Also, Tony Clayton has a wonderful webpage on Metals Used in Coins and Medals. It has some fascinating details about the history of these metals and their alloys in coinage. For example, “In Old English the Latin word aes was rendered as brass, thus the use of the word brass to mean money still found today, especially in Northern England. “