Why Gold is Precious

The precious metals are those few that are not gasses, and not reactive. Of these, only gold (Au) and silver (Ag) are not extremely rare and hard to extract and work.

A while back, I posted a radio article by Planet Money on why gold is so valuable, and has been used for money for so long (God, Glory and GOLD: but why gold?). They’ve now created a nice video explaining the same thing. Though there’s less detail, the dramatic visuals (of the reactivity of sodium for example) make it quite interesting.

Making a Non-Stick Frying Pan the Old Fashioned Way: Creating Polymers at Home

"Seasoning" a cast iron frying pan creates a non-stick coating. (Image by Evan-Amos via Wikipedia).

Back in the day, if you wanted a non-stick cooking skillet, your best option was to do it yourself by seasoning a cast metal pan. Sheryl Canter has an excellent post describing the science behind the “seasoning” process. The key is to bake on a little bit of oil to create a strong cross-linked polymer surface. This is a nice tie into our discussion of polymers and polymerization in the middle school science class; although I’m not sure how many of my students have actually seen a cast iron pan, or even know what cast iron is.

Normal polymers are long molecules made up of smaller molecules linked together, much like a paperclip chain.
Cross-linked polymers are created when the long chained polymers are linked together by cross-links. It makes for a much sturdier molecule.

To season, you coat the pan with a thin layer of oil and bake it for a while (without anything in it). Baking releases free radicals from the metal that react with the oil to create a cross-linked polymer that’s really hard to break down or wear out, and prevent food from sticking to the pan. Different, cross linked polymers are used in car tires for their durability, but probably not for their lack of stickiness.

Apparently, linseed oil is the best seasoning agent, but it might be a bit hard to find.

Most non-stick, artificial surfaces, are also made of polymers of hydrocarbons, silicon oxides and other interesting chemicals.

Making a cross-linked polymer with borax and polyvinyl alcohol.

In the lab, you can make your own cross-linked polymer “slime” by adding a solution of borax (sodium tetraborate) to a solution of polyvinyl alcohol (1:1 ratio of concentrations) (Practical Chemistry, 2008).

The result is a satisfying goo.

Cross-linked polymer "slime".

Science Starts with Careful Observation

Page 1 of my notes: Diagram of our mysterious mixture.
Sealed jar with a number of unknown substances.

The middle school started science this week with a mysterious jar of unknown substances: a couple immiscible liquids; some plastics and metals of different densities.

As they try to separate and identify the mixture they’ll be learning about handling potentially hazardous materials, material physical and chemical properties (like density and pH), and a little chemistry.

But the first thing they need to learn is how to take notes. Science starts (and ends) with observation. Careful observation. And most middle schoolers need mentoring to make sure their notes are rigorous.

To this end, after they wrote up their observations of what was in the jar, I put together my own notes as a general reference. This is not the only way to take notes, but I’m going to have them amend their own notes to make sure they’re neater and have as much detail as possible.

Page 2 of notes on the mysterious jar.
Page 3 of notes on the mysterious jar.

Crystals, Non-Crystals and Quasicrystals

Quasicrystalline ordering of a aluminum-palladium-manganese alloy. Image by J.W.Evans via Wikipedia.
Regular ordering of a halite crystal. The atoms that make up salt crystals are arranged in a cubic shape. The smaller grey atoms are sodium (Na), and the larger green ones are chlorine (Cl).

Daniel Shechtman was just awarded the Nobel Prize in Chemistry (2011). He discovered that matter can exist not only as crystals, which have a regular geometric arrangement of atoms, and amorphous non-crystals that do not, but also as quasicrystals which have a different type of atomic ordering.

The Guardian has an interesting article on Schechtman, whose discovery was roundly disbelieved by other scientists and he was ridiculed for years.

In an interview this year with the Israeli newspaper, Haaretz, Shechtman said: “People just laughed at me.” He recalled how Linus Pauling, a colossus of science and a double Nobel laureate, mounted a frightening “crusade” against him. After telling Shechtman to go back and read a crystallography textbook, the head of his research group asked him to leave for “bringing disgrace” on the team. “I felt rejected,” Shachtman said.

— Sample (2011): Nobel Prize in Chemistry for dogged work on ‘impossible’ quasicrystals in The Guardian

Hat tip to M. Eisenberg for this link.

Superfund Sites in Your Area – And Other Environmental Cleanups in Your Community

EPA's Cleanups in My Community map for St. Louis and its western suburbs.

Want to find your nearest superfund site? The EPA has an interactive page called, Clean Up My Community, that maps brownfields, hazardous waste, and superfund sites anywhere in the U.S.

Note:

  • Brownfields are places, usually in cities, that can’t be easily re-developed because there’s some existing pollution on the site.
  • Superfund sites are places where there is hazardous pollution that the government is cleaning up because the companies that caused the pollution have gone out of business, or because the government caused the pollution in the first place. The military is probably the biggest source of government pollution, particularly from fuel leaks and radioactive waste.

3d Molecule of the Month

Cyclohexane, from the interactive model on 3Dchem.com.

Molecular models tend to fascinate. As a introduction to the chemistry of elements, students seem to like putting them together, and they tend to enjoy finding out what their molecules are called.

You can’t beat fitting together molecules by hand as a learning experience, but 3Dchem has a nice collection of interactive, three-dimensional molecules, including molecules of the month.

Periodic spiral of the elements (from 3Dchem.com).

They also have three-dimensional periodic tables showing the sizes of the atoms in the traditional tabular form as well as a spiral.

Periodic Table showing the elements by size.

Periodic Table Spiral Galaxy

The objective is to show the shape of the whole and to express the beauty and cosmic reach of the periodic system.

— Stewart (2006): The Chemical Galaxy

Chemical Galaxy II: A new vision of the periodic system of the elements by Philip Stewart.
Periodic Table of the Elements - a traditional view by Wikimedia Commons User:Cepheus.

The traditional periodic table of the elements breaks the elements into rows as their chemical and physical characteristics repeat themselves. But since the sequence of elements is really a continuous series that gradually increases in mass, a better way of displaying them might be as the spiral, sort of like the galaxy.

When the chemical elements are arranged in order of their atomic number, they form a continuous sequence, in which certain chemical characteristics come back periodically in a regular way. This is usually shown by chopping the sequence up into sections and arranging them as a rectangular table. The alternative is to wind the sequence round in a spiral. Because the periodic repeats come at longer and longer intervals, increasing numbers of elements have to be fitted on to its coils. …

The resulting pattern resembles a galaxy, and the likeness is the basis of my design. It seems appropriate, as the chemical elements are what galaxies are made of.

The ‘spokes’ of the ‘galaxy’ link together elements with similar chemical characteristics. They are curved in order to keep the inner elements reasonably close together while making room for the extra elements in the outer turns.

— Stewart (2006): The Chemical Galaxy

While the spiral version of the periodic table is not used a lot, it is scientifically valid. There are other ways of representing the spiral and the periodic table itself. It all depends on what you want to show.

Benfey's spiral table first appeared in an article by Glenn Seaborg, 'Plutonium: The Ornery Element', Chemistry, June 1964, 37 (6), 12-17, on p. 14. (via Wikimedia Commons)

Indeed, Mendeleev’s monument in Bratislava, Slovakia has the elements arranged as the spokes in a wheel.

Monument to the periodic table and Dmitri Mendellev (photo by mmmdirt, caption via Wikipedia).

Phosphorus: What is it good for?

So other than digging in Morocco, where do we get more phosphorus? Here’s a hint: the symbol for phosphorus on the periodic table… is “P.”

— Horwich (2011): The end of phosphorus on APM’s Marketplace.

Marketplace’s Jeff Horwich has an excellent article on the uses of the element phosphorus, where it comes from, why it’s getting scarce, and where we might get more.

The answers to these questions are:

  • It’s a key element in DNA, so the major use is fertilizer,
  • most of it comes from Morocco these days,
  • since Morocco supplies about 85% of the world supply, they’re developing a bit of a monopoly and the price is going up,
  • the main alternative sources are manure and urine that have lots of phosphorous. In fact, burning sewage leaves behind a phosphorous rich ash.

Marketplace tells the story in much more detail.