Elements can be identified from the color of light they give off when they’re ionized: their emission spectra. Ms. Wilson’s chemistry class today set fire to some metal salts to watch them burn.
A hydrogen atom's electron is bumped up an energy level/shell by ultraviolet light, but releases that light when the electron drops back down to its original shell.
She placed the salt crystals into petri dishes, submerged them in a shallow layer of alcohol, and ignited the alcohol. As traces of the salts were incorporated into the flames, the metal atoms became “excited” as they absorbed some of the energy from the flame by bumping up their electrons into higher electron shells. Since atoms don’t “like” to be excited, their excited electrons quickly dropped back to their stable, ground state, but, in doing so, released the excess energy as light of the characteristic wavelength.
Using stopwatches, we measured the time it took for the tennis ball to fall 5.3 meters. Some of the individual measurements were off by over 30%, but the average time measured was only off by 7%.
I did a little exercise at the start of my high-school physics class today that introduced different types of experimental error. We’re starting the second quarter now and it’s time for their lab reports to including more discussion about potential sources of error, how they might fix some of them, and what they might mean.
One of the stairwells just outside the physics classroom wraps around nicely, so students could stand on the steps and, using stopwatches, time it as I dropped a tennis ball 5.3 meters, from the top banister to the floor below.
Students' measured falling times (in seconds).
Random and Reading Errors
They had a variety of stopwatches, including a number of phones, at least one wristwatch, and a few of the classroom stopwatches that I had on hand. Some devices could do readings to one hundredth of a second, while others could only do tenths of a second. So you can see that there is some error just due to how detailed the measuring device can be read. We’ll call this the reading error. If the best value your stopwatch gives you is to the tenth of a second, then you have a reading error of plus or minus 0.1 seconds (±0.1 s). And you can’t do much about this other than get a better measuring device.
Another source of error is just due to random differences that will happen with every experimental trial. Maybe you were just a fraction of a second slower stopping your watch this time compared to the last. Maybe a slight gust of air slowed the balls fall when it dropped this time. This type of error is usually just called random error, and can only be reduced by taking more and more measurements.
Our combination of reading and random errors, meant that we had quite a wide range of results – ranging from a minimum time of 0.7 seconds, to a maximum of 1.2 seconds.
So what was the right answer?
Well, you can calculate the falling time if you know the distance (d) the ball fell (d = 5.3 m), and its acceleration due to gravity (g = 9.8 m/s2) using the equation:
which gives:
So while some individual measurements were off by over 30%, the average value was off by only 8%, which is a nice illustration of the phenomenon that the more measurements you take, the better your result. In fact, you can plot the improvement in the data by drawing a graph of how the average of the measurements improves with the number of measurements (n) you take.
The first measurement (1.2 s) is much higher than the calculated value, but when you incorporate the next four values in the average it undershoots the actual (calculated) value. However, as you add more and more data points into the average the measured value gets slowly closer to the calculated value.
More measurements reduce the random error, but you tend to get to a point of diminishing returns when you average just does not improve enough to make it worth the effort of taking more measurements. The graph shows the average slowly ramping up after you use five measurements. While there are statistical techniques that can help you determine how many samples are enough, you ultimately have to base you decision on how accurate you want to be and how much time and energy you want to spend on the project. Given the large range of values we have in this example, I would not want to use less than six measurements.
Systematic Error
But, as you can see from the graph, even with over a dozen measurements, the average measured value remains persistently lower than the calculated value. Why?
This is quite likely due to some systematic error in our experiment – an error you make every time you do the experiment. Systematic errors are the most interesting type of errors because they tell you that something in the way you’ve designed your experiment is faulty.
The most exciting type of systematic error would, in my opinion, be one caused by a fundamental error in your assumptions, because they challenge you to fundamentally reevaluate what you’re doing. The scientists who recently reported seeing particles moving faster than light made their discovery because there was a systematic error in their measurements – an error that may result in the rewriting of the laws of physics.
In our experiment, I calculated the time the tennis ball took to fall using the gravitational acceleration at the surface of the Earth (9.8 m/s2). One important force that I did not consider in the calculation was air resistance. Air resistance would slow down the ball every single time it was dropped. It would be a systematic error. In fact, we could use the error that shows up to actually calculate the force of the air resistance.
However, since air resistance would slow the ball down, it would take longer to hit the floor. Unfortunately, our measurements were shorter than the calculated falling time so air resistance is unlikely to explain our error. So we’re left with some error in how the experiment was done. And quite frankly, I’m not really sure what it is. I suspect it has to do with student’s reaction times – it probably took them longer to start their stopwatches when I dropped the ball than it did to stop them when the ball hit the floor – but I’m not sure. We’ll need further experiments to figure this one out.
In Conclusion
On reflection, I think I probably would have done better using a less dense ball, perhaps a styrofoam ball, that would be more affected by air resistance, so I can show how systematic errors can be useful.
Fortunately (sort of) in my demonstration I made an error in calculating the falling rate – I forgot to include the 2 under the square root sign – so I ended up with a much lower predicted falling time for the ball – which allowed me to go through a whole exercise showing the class how to use Excel’s Goal Seek function to figure out the deceleration due to air resistance.
My Excel Spreadsheet with all the data and calculations is included here.
There are quite a number of other things that I did not get into since I was trying to keep this exercise short (less than half an hour), but one key one would be using significant figures.
There are a number of good, but technical websites dealing with error analysis including this, this and this.
Collapsed milk jug.
Place a little hot water (400 ml at 94-100°C) into a plastic, gallon-sized, milk jug. Give it a moment to warm the air in the jug, then put the cap on and seal tightly (hopefully airtightly).
As the air in the jug cools the gas inside with shrink, reducing its pressure, and causing the atmospheric pressure to push in the sides of the jug.
Admittedly, this experiment is a little more dramatic if you use a metal tin, but it works well enough with the milk jug to surprise and impress.
